Effect of Electrode Configuration and Transition Time in Solid Electrode Chronopotentiometry
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Chronopotentiometric Measurements of Chemical Reaction Rates , Programmed Current Studies of the ECE Mechanism ' I
Programmed current chronopotentiometry, specifically current reversal and current decrease, is applied to electrode reactions characterized by a chemical reaction coupled between two charge-transfer reactions, the ECE mechanism. The equations for the transition times are derived and solved. Current-reversal results on systems following the ECE mechanism, p-nitrosophenol, p-nitrophenol, and o-ni...
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تاریخ انتشار 2009